Sulphur dioxide (SO2) enters the atmosphere as a results of both natural
phenomena and anthropogenic activities, such as fossil fuel combustion,
oxidation of organic materials in soils, volcanic eruptions and biomass
burning. SO2 contributes to acid rain and it is a key precursor for
sulphuric acid aerosol formation. At high concentration, it also adversely
affects human health, in particular in combination with fog (smog).
Changes in the abundance of SO2 have an impact on atmospheric chemistry and
hence on air quality and on climate. Effects of volcanic eruptions may have
an impact on air traffic, as such eruptions are important sources of ash
(aerosols) and SO2. Consequently, global observations of SO2 are important
for atmospheric and climate research, and for air traffic organisations.
Global monitoring of SO2 concentrations is done on the basis of UV-Visible
measurements by satellite based nadir-viewing instruments. Local monitoring,
notably around volcanoes, is done using ground-based instruments.
SO2 measured by the SCIAMACHY instrument around Reunion Island, after the
eruption of the Piton de la Fournaise volcano which started early April
2007.
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SO2 released in the atmosphere due to anthropogenic activities will usually
stay in the lower atmosphere, the troposphere, and from there it is
transported by winds. It is removed from the troposphere:
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in gas phase by formation of sulphuric acid (H2SO4),
which forms condensation nuclei for aerosols and clouds and
acidifies the rain;
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directly, by way of an uptake on aerosols and clouds,
which leads to dry and wet acid depositions.
The elevation reached by SO2 of volcanic origin depends on the kind of
volcano, on the kind of eruption: for some eruptions the SO2 will stay
relatively close to the ground, while explosive eruptions may take the SO2
high up into the statosphere, up to 15 km or more. Once in the
stratosphere, the lifetime of SO2 is several weeks, during which it produces
sulphate aerosols. This makes sulphur dioxide from volcanos one of the two
most important sources of stratospheric aerosols.
Data products & projects
Within the UV-Vis/DOAS group SO2 is retrieved from measurements made by
several instruments (these data pages are maintained outside the group):
The data is retrieved and/or made available within the framework of several
services and projects (links lead to the respective project websites):
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